A rubber composition which can be used in particular in tires, based on at least one diene elastomer, one reinforcing filler, one crosslinking system, one phenolic resin and one polyaldehyde. The use of a polyaldehyde makes it possible to advantageously replace conventional methylene donors while preventing the production of formaldehyde during the vulcanization of the rubber compositions and thus to limit the environmental impact of these compounds. Furthermore, these polyaldehyde compounds make it possible not only to obtain rubber compositions exhibiting the same low-strain stiffness as conventional rubber compositions using HMT or H3M methylene donors but also, surprisingly, to greatly improve the fatigue strength of the rubber compositions and thus the endurance of the tires.

Veyland; Anne

Araujo Da Silva; Jose Carlos

Hunault; Vincent

Michelin Recherche et Technique S.A.

COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN

Rubber composition including a phenolic resin

A multi-step stabilization method for connective tissue is described. Stabilized tissues can exhibit increased resistance to degradation due to enzyme activity, fatigue and storage. The multi-step method includes a first step during which the tissue can be incubated with a glycosaminoglycanase inhibitor such as a sulfated oligosaccharide, one example of which being neomycin, a second step during which the tissue can be incubated with a crosslink activator such as a carbodiimide crosslink activator and/or a crosslinking agent such as a heterobifunctional crosslinking agent and/or a phenolic compound such as a tannin, examples of which include tannic acid and pentagalloylglucose, and a third step during which the tissue can be incubated with a second crosslink activator that can be the same or different as the first crosslink activator.

Clemson University

Multi-step connective tissue stabilization method and stabilized tissue formed thereby

The present invention provides a carbon fiber cord having both high bending fatigue resistance and high adhesiveness. The disclosed carbon fiber cord is a carbon fiber cord for reinforcing a rubber product. This carbon fiber cord includes a carbon fiber, a first coating layer formed on the carbon fiber, and a second coating layer formed over the first coating layer. The first coating layer contains a phenolic resin and does not contain a rubber component. The second coating layer contains a rubber component. The mass ratio of the first coating layer to the total mass of the carbon fiber and the first coating layer is in a range of 0.5% to 10%.

Nippon Sheet Glass Company, Limited

NIPPON SHEET GLASS COMPANY, LIMITED

Carbon fiber cord for reinforcing rubber product and rubber product using the same

phenolic

umor

fatigue

phenolic/umor

Rubber composition including a phenolic resin

Multi-step connective tissue stabilization method and stabilized tissue formed thereby

Carbon fiber cord for reinforcing rubber product and rubber product using the same

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