geranyl pyrophosphate/timian

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Hydride shifts in the biosynthesis of the p-menthane monoterpenes alpha-terpinene, gamma-terpinene, and beta-phellandrene.

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The biosynthesis of several monoterpenes from the acyclic precursor geranyl pyrophosphate requires the migration of positive charge from the isopropyl side chain into the cyclohexenoid ring of the universal alpha-terpinyl cation intermediate of the reaction. The hydride shifts responsible for charge

Purification and characterization of the monoterpene cyclase gamma-terpinene synthase from Thymus vulgaris.

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The monoterpene cyclase, gamma-terpinene synthase, from Thymus vulgaris (thyme) leaves was purified to apparent homogeneity by isoelectric focusing and dye-ligand, anion-exchange, hydrophobic interaction, and gel permeation chromatography. The enzyme has a native molecular weight of 96,000 as

Functional characterization of a new terpene synthase from Plectranthus amboinicus

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Plectranthus amboinicus (Lour.) Spreng is an aromatic medicinal herb known for its therapeutic and nutritional properties attributed by the presence of monoterpene and sesquiterpene compounds. Up until now, research on terpenoid biosynthesis has focused on a few mint species with economic importance

Localization of the biosynthesis and accumulation of monoterpenoids in glandular trichomes of thyme.

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Quantitative analyses of the essential oils in intact glandular trichomes isolated from thyme cotyledons by the use of an adhesive tape and a glass capillary tube showed that the content of thymol per cotyledon was approximately equal to the sum total of thymol in peltate glandular trichomes (PGTs)

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