Chemical Communications 2010-Jun

Chirality from achiral components: N,N'-bis(4-dimethylaminobenzyl)dodecane-1,12-diammonium in cucurbit[8]uril.

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Xin Xiao

Jing-Xin Liu

Zhi-Fang Fan

Kai Chen

Qian-Jiang Zhu

Sai-Feng Xue

Zhu Tao

ARTICLE: 20419185

DOI: 10.1039/b927592d

BioSeek: 20419185

Keywords

Abstract

The long alkyl chain of N,N'-bis(4-dimethylaminobenzyl)dodecane-1,12-diamine (C(12)DA) adopts different chiral helical conformations, one left-handed and the other right-handed, when bound within the cavities of two distorted cucurbit[8]uril (Q[8]) units, as unequivocally established by X-ray crystallography.

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Chirality from achiral components: N,N'-bis(4-dimethylaminobenzyl)dodecane-1,12-diammonium in cucurbit[8]uril.

Keywords

dental caries

dodecane

Abstract

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