Assessment and optimization of the use of a novel natural coagulant (Guazuma ulmifolia) for dairy wastewater treatment

A feasible, novel, and natural coagulant extracted from G. ulmifolia stem bark was characterized and used in experiments of coagulation/dissolved air flotation (C/DAF) to treat synthetic dairy wastewater (SDW). The performance of G. ulmifolia to remove turbidity, chemical oxygen demand (COD), and UV₂₅₄ was evaluated by using response surface methodology (Doehlert matrix). G. ulmifolia dosage and pH were evaluated and optimized in the C/DAF process and its characterization was performed by Fourier Transform Infrared (FTIR) spectroscopy, Scanning Electron Microscopy (SEM), and also zeta potential. Results showed that G. ulmifolia stem bark is composed of large quantities of condensed tannins represented by the groups C=C-C and CO of pyran (flavonoid C-rings), which serve as bridges during coagulation. Moreover, the presence of porous cavities in surface of G. ulmifolia, shown by SEM, indicated capacity for adsorption. G. ulmifolia dosage and pH were significant (p ≤ 0.05) for pollutant removal from the SDW. Jar test results revealed that 95.8% of turbidity, 76.0% of COD, 81.2% of BOD, and 85.6% of UV₂₅₄ were removed from SDW by using G. ulmifolia stem bark at a dose of 775.8 mg L^-1 and pH 5.00. Finally, our results showed promising use of G. ulmifolia as a coagulating agent due to its novelty, efficiency, low-cost, and eco-friendly properties as an alternative for the treatment of dairy wastewaters.

Keywords: Coagulation; Dissolved air flotation; Doehlert matrix; Milk effluent; Mutamba; West Indian elm.