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4 results
Investigation of biosynthetic pathways to hydroxycoumarins during post-harvest physiological deterioration in Cassava roots by using stable isotope labelling.
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Cassava (Manihot esculenta Crantz) is an important starch-rich crop, but the storage roots only have a short shelf-life due to post-harvest physiological deterioration (PPD), which includes the over-production and polymerisation of hydroxycoumarins. Key aspects of coumarin secondary-metabolite
Electron transfer between protonated and unprotonated phenoxyl radicals.
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The reaction of phenoxyl radicals with acids is investigated. 2,4,6-Tri-tert-butylphenoxyl radical (13), a persistent radical, deteriorates in MeOH/PhH in the presence of an acid yielding 4-methoxycyclohexa-2,5-dienone 18a and the parent phenol (14). The reaction is facilitated by a strong acid.
Energy barriers of vinylidene carbene reactions from the anti-hermitian contracted Schrödinger equation.
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Computational studies of carbenes must take into account the possibility of multireference correlation because the highest occupied and lowest unoccupied molecular orbitals can be nearly energetically degenerate. We apply the anti-Hermitian contracted Schrodinger equation (ACSE) [Mazziotti, D. A.
Bracken carcinogens in the human diet.
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The ubiquitous bracken fern (genus Pteridium) is the only higher plant known to cause cancer naturally in animals. In addition to the well-recognized syndromes of thiamine deficiency, acute haemorrhage associated with myeloid aplasia and blindness due to retinal degeneration, it causes neoplasia of
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