dienone/pentas

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3,4-Diphenyl-2,5-bis-(trimethyl-silyl)cyclo-penta-dienone.

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In the title compound, C(23)H(28)OSi(2), the five-membered ring is essentially planar and the phenyl rings are oriented with respect to the mean plane of this ring by 56.01 (3) and 56.68 (4)°.

Noncovalent DNA binding drives DNA alkylation by leinamycin: evidence that the Z,E-5-(thiazol-4-yl)-penta-2,4-dienone moiety of the natural product serves as an atypical DNA intercalator.

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Molecular recognition and chemical modification of DNA are important in medicinal chemistry, toxicology, and biotechnology. Historically, natural products have revealed many interesting and unexpected mechanisms for noncovalent DNA binding and covalent DNA modification. The studies reported here

4,5-Dihydro-cyclo-penta-[b]thio-phen-6-one.

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The title compound, C(7)H(6)OS, crystallizes with two similar mol-ecules, 1 and 2, in the asymmetric unit. Both mol-ecules are essentially planar with r.m.s. deviations of 0.0193 and 0.0107 Å for the planes through the nine non-H atoms of mol-ecules 1 and 2, respectively. The thio-phene and

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