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necine/eupatorium

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Investigation into the Presence of Pyrrolizidine Alkaloids in Eupatorium cannabinum by Means of Positive and Negative Ion Chemical Ionization GC-MS.

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It is demonstrated that the combination of positive ion chemical ionization and negative ion chemical ionization GC-MS analyses of herb and root extracts of EUPATORIUM CANNABINUM L. offers a rapid, tentative structure elucidation of pyrrolizidine alkaloids (PAs). Compounds identified in aerial parts

Polyphyletic origin of pyrrolizidine alkaloids within the Asteraceae. Evidence from differential tissue expression of homospermidine synthase.

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The evolution of pathways within plant secondary metabolism has been studied by using the pyrrolizidine alkaloids (PAs) as a model system. PAs are constitutively produced by plants as a defense against herbivores. The occurrence of PAs is restricted to certain unrelated families within the
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