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dichloromethane/dental caries
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Molecular dynamics of a calix[4]arene-containing polymer in dichloromethane solution: ability of the solvent molecules to fill the cavity of the macrocycle.
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The structure and dynamics of the dichloromethane solvent around the calix[4]arene units contained in the molecular actuator poly(calix[4]arene bis-bithiophene) have been examined using a 1-micros molecular dynamics simulation. Results indicate that a solvent molecule fills the cavity associated to
Frozen Dissymmetric Cavities in Resorcinarene-Based Coordination Capsules.
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By introducing slight structural modifications to a D4 -symmetric coordination capsule, we succeeded in isolating the nearly enantiopure capsules (P)- and (M)-2 a(BF4 )4 . Chiral guest, dibenzyl 4,4'-diacetoxy-6,6'-dimethyl-[1,1'-biphenyl]-2,2'-dicarboxylate (3) was encapsulated within the
Locking high energy 1D chain of dichloromethane molecules containing abnormally short Cl···Cl contacts of 2.524 Å inside organic crystals.
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1D helical channels can be created by "sticky" end-mediated formation of 1D helical stacks composed of short cavity-containing helices and are able to host 1D chains of dichloromethane molecules containing extraordinarily short intermolecular Cl···Cl contacts of 2.524 Å in length that
Inclusion complexes of cryptophane-E with dichloromethane and chloroform: A thermodynamic and kinetic study using the 1D-EXSY NMR method.
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Complexation equilibria and kinetics of exchange of chloroform and dichloromethane molecules between the cavity of cryptophane-E and bulk solution were investigated using NMR methods. Using one-dimensional magnetization transfer (1D-EXSY type sequence), chemical exchange rates were measured in
NTP Toxicology and Carcinogenesis Studies of Dichloromethane (Methylene Chloride) (CAS No. 75-09-2) in F344/N Rats and B6C3F1 Mice (Inhalation Studies).
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Dichloromethane is widely used in industrial processes, food preparation, and agriculture. In industry, dichloromethane is used as a solvent in paint removers, degreasing agents, aerosol propellants, and triacetate solutions; as a blowing agent in flexible urethane foams; and as a process solvent in
The host-guest complex between cone-25,26:27,28-bis(methylenedioxy)calix[4]arene and dichloromethane.
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The title compound, 25,26:27,28-bis(methylenedioxy)pentacyclo[19.3.1.1(3,7).1(9,13).1(15,19)]octacosa-1(25)3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaene dichloromethane solvate, C(30)H(24)O(4).CH(2)Cl(2), possesses crystallographic twofold symmetry in both components. The calixarene shows a
Antimicrobial activity of fractions and subfractions of Elaeagia utilis against microorganisms of importance in dental caries.
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Dental caries is a multifactorial infectious disease that leads to the destruction of dental hard tissue. The main goal of research into medicinal plants is to seek compounds with antimicrobial activity for subsequent use in prevention strategies and control of infectious diseases. The aim of this
In vitro anti-cariogenic activity of dichloromethane fraction from Rheum undulatum L. root.
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This study aimed to evaluate in vitro effects of Rheum undulatum L. root on the development of dental caries, especially its effects on viability, dental plaque formation, and glycolytic acid production of Streptococcus mutans and Streptococcus sobrinus. Methanol extract of Rheum undulatum L. root
Modulatory effect of Senecio brasiliensis (Spreng) Less. in a murine model of inflammation induced by carrageenan into the pleural cavity.
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BACKGROUND
Senecio brasiliensis (Spreng) Less (S. brasiliensis), known as "Flor-das-almas", "Margaridinha" or "Maria mole", is used in folk medicine as an anti-inflammatory and to treat gastric ulcers and stomach pain. While the Senecio genus has been widely studied for its pharmacological
Cytotoxic activity of the dichloromethane fraction from Vernonia scorpioides (Lam.) Pers. (Asteraceae) against Ehrlich's tumor cells in mice.
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Vernonia scorpioides has been widely used in Brazil to treat skin problems and chronic wounds, such as ulcers of the lower limbs and diabetic lesions. In the present study, we investigated the effect of a dichloromethane (DCM) fraction of V. scorpioides leaf extract on Ehrlich ascitic and solid
1H-NMR studies on the ternary complexes of rare-earth ions with thenoyltrifluoroacetone and polyethers in dichloromethane.
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The structures of the ternary complexes of lanthanoid and yttrium (Ln3+)-thenoyltrifluoroacetonates (tta-) with polyether (POE) in organic phase were investigated by 1H-NMR spectroscopy, where the POEs are crown ethers (18-crown-6 and benzo-18-crown-6) and monodispersed linear polyethers (DEOn:
Beneficial effect of Ageratum conyzoides Linn (Asteraceae) upon inflammatory response induced by carrageenan into the mice pleural cavity.
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BACKGROUND
Ageratum conyzoides Linn (Asteraceae), a tropical plant that is very common in West Africa and some parts of Asia and South America, has been used to treat inflammatory disorders. In Brazil, teas made from A. conyzoides L. are used as anti-inflammatory, analgesic and anti-diarrheic
Temperature-controlled headspace liquid-phase microextraction device using volatile solvents.
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A novel temperature-controlled headspace liquid-phase microextraction (TC-HS-LPME) device was established in which volatile solvents could be used as extractant. In this device, a PTFE vial cap with a cylindrical cavity was used as the holder of the extraction solvent. Up to 40 microl of extraction
Spectroscopic signatures of halogens in clathrate hydrate cages. 1. Bromine.
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We report the first UV-vis spectroscopic study of bromine molecules confined in clathrate hydrate cages. Bromine in its natural hydrate occupies 51262 and 51263 lattice cavities. Bromine also can be encapsulated into the larger 51264 cages of a type II hydrate formed mainly from tetrahydrofuran or
A neutral cluster cage with a tetrahedral [Pd12(II)L6] framework: crystal structures and host–guest studies.
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A charge-neutral tetrahedral [(Pd3X)4L6] cage assembly built from a trinuclear polyhedral building unit (PBU), [Pd3X](3+), cis-blocked with an imido P(V) ligand, [(N(i)Pr)3PO](3-) (X(3-)), and oxalate dianions (L(2-)) is reported. Use of benzoate or ferrocene dicarboxylate anions, which do not offer
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