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Phytochemistry 2011-Apr

Chemical constituents from fruits of Harrisonia perforata.

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Xiao-Hui Yan
Ying-Tong Di
Xin Fang
Shi-Ying Yang
Hong-Ping He
Shun-Lin Li
Yang Lu
Xiao-Jiang Hao

Ključne riječi

Sažetak

Eight limonoids (1-8) including three A, B and D-seco-16-nor-type ones, 5,6-dehydrodesepoxyharperforin C2 (1), harrpernoid B (2), and its C-9S epimer, harrpernoid C (3), along with six known compounds (9-14), were isolated from fruits of Harrisonia perforata. Extensive spectroscopic analysis was used to elucidate their structures and stereochemistries. Further confirmation of structures of 1 and 2 were obtained by single-crystal X-ray diffraction. Limonoids (1-8) were evaluated for their anti-tobacco mosaic virus activity and in vitro cytotoxicity against A549 and HL60 cell lines; only compound 2 showed weak activity.

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