Monitoring Ambient Nitrate Radical by Open-Path Cavity-Enhanced Absorption Spectroscopy.

We describe an open-path cavity-enhanced absorption spectroscopy (OP-CEAS) technique for the ambient measurement of nitrate radicals (NO₃) near 662 nm. Compared with the closed type of CEAS system with a sampling line, the OP-CEAS features high accuracy due to the lack of NO₃ loss in the sampling line and cavity. On the basis of a 0.84 m long open-path cavity, the effective absorption length of ∼5 km is achieved by mirrors with a reflectivity of 0.99985 at 662 nm. The detection limit of OP-CEAS for the measurement of NO₃ is 3.0 pptv (2σ) in 30 s, and the uncertainty is 11-15%. The instrument was successfully applied in a field measurement under low particulate matter (PM) loading conditions. As the sensitivity would be decreased due to strong PM extinction under heavy PM pollution conditions, we highlight the feasibility of this OP-CEAS configuration for field application in clean and moderate PM condition, such as forested regions affected by anthropogenic emissions. This technique is also appropriate for the field detection of other reactive trace gases in future studies.