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trans cinnamic acid/dental caries
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The crystal structure of the 1:1 complex of beta-cyclodextrin with trans-cinnamic acid.
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The crystal structure of the 1:1 complex of beta-cyclodextrin (cyclomaltoheptaose) with trans-cinnamic acid was studied by X-ray diffraction. Two beta-cyclodextrin molecules related by a twofold crystal axis form dimers in the hydrophobic cavity of which, two guest molecules are entirely buried. The
Templating photodimerization of trans-cinnamic acid esters with a water-soluble Pd nanocage.
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A water-soluble octahedral Pd nanocage acting as a reaction vessel templates the photodimerization of substituted trans-cinnamic acid methyl esters in water. Irradiation of the host-guest complexes of trans-cinnamic acid methyl esters with the Pd nanocage resulted in selective formation of a syn
Templating photodimerization of trans-cinnamic acids with cucurbit[8]uril and gamma-cyclodextrin.
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Cucurbit[8]uril and gamma-cyclodextrin are able to align two olefin molecules in a head-head fashion within their large cavities. Excitation of such templated olefins results in syn head-head cyclobutanes in nearly quantitative yields. The methodology revealed here works with trans-cinnamic acids
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