Chemical Communications 2005-Jun
Nano-dimensions for the pyrogallol[4]arene cavity.
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The cup-like cavity of pyrogallol[4]arenes has been deepened by the addition of four hydrogen bonded bipyridine molecules to the upper-rim of the calixarene, enabling the extended cup-like molecules to stack inside one another and consequently trap and completely enshroud a single guest molecule within the 250 angstroms3 cavitand formed between two of these stacked "nano-cups".