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hydrocarbon/carie dentaria
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[Distribution character of polycyclic aromatic hydrocarbons in soils from the karst cavity, Guilin City, South China].
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We investigated the distribution characteristic of polycyclic aromatic hydrocarbons (PAHs) of soils from Dayan cave, a karst cavity in Guilin City, South China. The total PAHs concentrations from the inner cave ranged from 7.22 to 117.29 ng x g(-1) were much lower than those of outside cave (range
Jet-discharge cavity ring-down spectroscopy of ionized polycyclic aromatic hydrocarbons: progress in testing the PAH hypothesis for the diffuse interstellar band problem.
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Naphthalene cations (C10H+8) were produced in a slit jet coupled with an electronic discharge, and cavity ring down was used to obtain its absorption spectrum in the region 645-680 nm. Two of the strongest C10H+8 bands previously characterized by matrix isolation spectroscopy were found, both with a
Carcinoma of the oral cavity in relation to aryl hydrocarbon hydroxylase inducibility, smoking and dental status.
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The authors investigated the smoking patterns in a consecutive series of 20 patients with oral cancer and at the same time assessed the aryl hydrocarbon hydroxylase (AHH) inducibility distribution and dental status. The AHH level proved high in 8 patients, intermediate in 7 and low in 5. High AHH
Henry's law constant of hydrocarbons in air-water system: the cavity ovality effect on the non-electrostatic contribution term of solvation free energy.
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In this study, a quantitative structure-property relationship (QSPR) model for the prediction of Henry's law constants of aliphatic hydrocarbons in air-water system has been developed, based on a data-set of 189 compounds. The well-known linear thermodynamic relation between the logarithm of Henry's
Infrared cavity ringdown spectroscopy of jet-cooled polycyclic aromatic hydrocarbons.
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Infrared absorption spectra of the CH stretching region were observed for naphthalene, anthracene, phenanthrene, pyrene, and perylene using a heated, supersonic, slit-jet source and cavity ringdown spectroscopy. Band positions and intensities recorded with 0.2-cm-1 resolution were compared with
Occupational exposures to asbestos, polycyclic aromatic hydrocarbons and solvents, and cancers of the oral cavity and pharynx: a quantitative literature review.
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OBJECTIVE
The role of occupational risk factors in oral and pharyngeal cancer is not well known and is possibly underestimated. This quantitative review summarizes epidemiological findings on exposure to asbestos, polycyclic aromatic hydrocarbons and solvents, and cancers of the oral cavity and
Competing electron-transfer pathways in hydrocarbon frameworks: short-circuiting through-bond coupling by nonbonded contacts in rigid U-shaped norbornylogous systems containing a cavity-bound aromatic pendant group.
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This work explores electron transfer through nonbonded contacts in two U-shaped DBA molecules 1DBA and 2DBA by measuring electron-transfer rates in organic solvents of different polarities. These molecules have identical U-shaped norbornylogous frameworks, 12 bonds in length and with
Conversion of methanol to hydrocarbons: how zeolite cavity and pore size controls product selectivity.
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Liquid hydrocarbon fuels play an essential part in the global energy chain, owing to their high energy density and easy transportability. Olefins play a similar role in the production of consumer goods. In a post-oil society, fuel and olefin production will rely on alternative carbon sources, such
Aryl hydrocarbon hydroxylase inducibility and carcinoma of oral cavity.
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Use of solvent cavity area and number of packed solvent molecules around a solute in regard to hydrocarbon solubilities and hydrophobic interactions.
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Two currently used methods of calculating the area of contact between a solute molecule and the solvent are examined and some important differences are pointed out. Some pitfalls and uncertainties in the application of the concept of molecular surface area to the quantitative estimation of unitary
The reactivity of molecules trapped within the SAPO-34 cavities in the methanol-to-hydrocarbons reaction.
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CYP63A2, a catalytically versatile fungal P450 monooxygenase capable of oxidizing higher-molecular-weight polycyclic aromatic hydrocarbons, alkylphenols, and alkanes.
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Cytochrome P450 monooxygenases (P450s) are known to oxidize hydrocarbons, albeit with limited substrate specificity across classes of these compounds. Here we report a P450 monooxygenase (CYP63A2) from the model ligninolytic white rot fungus Phanerochaete chrysosporium that was found to possess a
Intraperitoneal mesotheliomas induced in mice by a polycyclic aromatic hydrocarbon.
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Female mice of 6 strains (C3H/HeN, BALB/c, C57BL/6N, DBA/2, NIH Swiss, and AKR/N) were given the polycyclic aromatic hydrocarbon carcinogen 3-methylcholanthrene (MC) intragastrically in olive oil at a dose of 20 mg/kg, weekly for 12 wk. Half were pretreated 24 h before each MC administration with
Molecular recognition of hydrocarbon guests by a supramolecular capsule formed by the 4:4 self-assembly of tris(Zn(2+)-cyclen) and trithiocyanurate in aqueous solution.
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We have previously reported that the trimeric Zn(2+)-cyclen complex (tris(Zn(2+)-cyclen), [Zn(3)L(1)](6+)) and the trianion of trithiocyanuric acid (TCA(3-)) assembled in a 4:4 ratio to form a cuboctahedral supramolecular cage, [(Zn(3)L(1))(4)(TCA(3-))(4)](12+) (hereafter referred to as a Zn-cage),
Nanostructured alkyl carboxylic acid-based restricted access solvents: Application to the combined microextraction and cleanup of polycyclic aromatic hydrocarbons in mosses.
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Alkyl carboxylic acid-based nanostructured solvents, synthesized in mixtures of tetrahydrofuran (THF) and water through self-assembly and coacervation, were proved to behave as restricted access liquids. Both physical and chemical mechanisms were found responsible for exclusion of macromolecules
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