Organic and Biomolecular Chemistry 2014-Apr
Encapsulation and selectivity of sulfate with a furan-based hexaazamacrocyclic receptor in water.
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요약
A furan-based hexaazamacrocycle encapsulates a sulfate anion in its cavity showing strong affinity and selectivity for sulfate in water over a wide range of inorganic anions. The DFT calculations demonstrate that the receptor provides binding sites as hydrogen bonding donors and electrostatic positive charges for the strong binding of sulfate.