Chemical Communications 2011-Jan
A porphyrin-related macrocycle from carbazole and pyridine building blocks: synthesis and metal coordination.
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In this communication, we report the synthesis of a novel porphyrin-related macrocycle. The core modifications result in aromatic building blocks connected exclusively via aryl-aryl bonds. The concept of synthesis permits the formation of a cavity similar to that of a porphyrin combined with the ability to bind metal ions to provide neutral metal complexes.