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Bioresource Technology 2018-May

Investigating pyrolysis characteristics of moso bamboo through TG-FTIR and Py-GC/MS.

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Fang Liang
Ruijuan Wang
Xiang Hongzhong
Xiaomeng Yang
Tao Zhang
Wanhe Hu
Bingbing Mi
Zhijia Liu

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This study was carried out to investigate pyrolysis characteristics of moso bamboo (Phyllostachys pubescens), including outer layer (OB), middle layer (MB) and inner layer (IB) and bamboo leaves (BL), through TG-FTIR and Py-GC/MS. The results showed that 70% of weight loss occurred at rapid pyrolysis stage with temperature of 200-400 °C. With increase in heating rate, pyrolysis process shifted toward higher temperature. IB, OB, MB and BL had a different activation energy at different conversion rates. BL had a higher activation energy than IB, OB and MB. The volatiles of bamboo was complicated with 2-30 of C atoms. IB, OB and MB mainly released benzofuran, hydroxyacetaldehyde and 2-Pentanone. BL released furan, acetic acid and phenol. The main pyrolysis products included H2O, CH4, CO2, CO, carboxylic acids, NO, NO2. Pyrolysis products of IB was the most and that of BL was the lowest. MB had the lowest pyrolysis temperature.

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