Dalton Transactions 2011-Aug
Approaching polymetallic 'assemblies of assemblies' using ligands with multiple functionality--novel Mn10M2 (M = alkali metal) chains with 'ionophoric' end cavities.
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Abstrakt
A tri-functional ligand with hydrazone, oxime and o-vanillin subunits uses separate encoded coordination instructions to create a novel extended spin-coupled cluster where the hydazone oxygen and oxime groups of three ligands combine to create bridges linking ten Mn ions together, leaving organized O(6) end cavities capable of coordinating oxo-philic cations.