Organic and Biomolecular Chemistry 2012-Aug
Locking high energy 1D chain of dichloromethane molecules containing abnormally short Cl···Cl contacts of 2.524 Å inside organic crystals.
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Abstrakt
1D helical channels can be created by "sticky" end-mediated formation of 1D helical stacks composed of short cavity-containing helices and are able to host 1D chains of dichloromethane molecules containing extraordinarily short intermolecular Cl···Cl contacts of 2.524 Å in length that computationally destabilize the host-guest complex by 14.94 kcal mol(-1).