Acta crystallographica. Section E, Structure reports online 2010-Aug
5-(Hy-droxy-meth-yl)furan-2-carbaldehyde.
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The title compound (HMF), C(6)H(6)O(3), is one of the products of acid-catalyzed dehydration of high-fructose corn syrup, and has been shown to be toxic to honey bees. The compound was crystallized at 276 K, and it was found that the two independent mol-ecules in the asymmetric unit form an infinite O-H⋯O hydrogen-bonding chain that is linked into a three-dimensional network structure by weak inter-molecular C-H⋯O contacts.
