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8 resultat
Photophysical processes involved within the anisole-thioindoxyl dyad system.
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The photophysical properties and the nature of the photoinduced electron transfer (PET) reactions within a synthesized anisole (A)-thioindoxyl (T) dyad system (24MBTO) have been studied by electrochemical, steady-state, and time-resolved spectroscopic techniques. Computations on the dyad were
Peptide mimics by linear arylamides: a structural and functional diversity test.
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Hydrogen-bonded oligoamide foldamers represent a large family of peptide mimics. Pioneered by Gellman and Seebach (Appella , J. Am. Chem. Soc. 1996, 118, 13071- 13072; Seebach , Helv. Chim. Acta 1996, 79, 913- 941), aliphatic amino acid-based mimic structures have been extensively studied. Results
Structural requirements of para-alkylphenols to bind to estrogen receptor.
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Octyl- and nonylphenols in the environment have been proposed to function as estrogens. To gain insight into their structural essentials in binding to the estrogen receptor, a series of phenols with saturated alkyl groups at the para position, HO-C6H4-CnH2n+1 (n = 0-12), were examined for their
Metallocyclic receptors with Re(I)/Os(II)-based moieties: molecular photophysics and selective molecular sensing.
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New metallocyclic Re(I) and Os(II) complexes with polyphosphane/polyyne spacers, including dimers [(Re(CO)3Cl(C2nP2))2] (n = 1, 1; 2, 2) and tetramers [(Re(CO)3Cl(C2nP2))4] (n = 1, 3; 2, 4, C2P2 = Ph2P-C...C-PPh2, C4P2 = Ph2P-C...C-C...C-PPh2), as well as the mixed-metal
Spectral characteristics of tramadol in different solvents and beta-cyclodextrin.
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Effect of solvents and beta-cyclodextrin on the absorption and fluorescence spectra of tramadol drug has been investigated and compared with anisole. The solid inclusion complex of tramadol with beta-CD is investigated by FT-IR, (1)H NMR, scanning electron microscope (SEM), DSC and semiempirical
Enhanced and Heteromolecular Guest Encapsulation in Non-Porous Crystals of Perfluorinated Triketonato Dinuclear Copper Complex.
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Since the flexible host framework of perfluorinated mononuclear copper complex, [Cu(L1)2] (1, HL1 = 3-hydroxy-1,3-bis(pentafluorophenyl)-2-propen-1-one), with CuO4 core reversibly encapsulated several organic guest molecules through electrostatic interactions in their crystals, the corresponding
Microbial volatile organic compound emissions from Stachybotrys chartarum growing on gypsum wallboard and ceiling tile.
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BACKGROUND
Stachybotrys chartarum is a filamentous mold frequently identified among the mycobiota of water-damaged building materials. Growth of S. chartarum on suitable substrates and under favorable environmental conditions leads to the production of secondary metabolites such as mycotoxins and
Thermodynamics of host-guest interactions between fullerenes and a buckycatcher.
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(1)H NMR and isothermal titration calorimetry (ITC) experiments were employed to obtain reliable thermodynamic data for the formation of the 1:1 inclusion complexes of fullerenes C(60) and C(70) with the buckycatcher (C(60)H(28)). NMR measurements were done in toluene-d8 and chlorobenzene-d5 at 288,
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