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xiphidium/alkaloid

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Phenylbenzoisoquinolindione alkaloids accumulate in stamens of Xiphidium caeruleum Aubl. flowers.

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Xiphidium caeruleum (Haemodoraceae) flower organs such as carpels, pedicels, petals, and stamens were separately investigated for their phytochemical profile. The stamens appeared to be a rich source of previously undescribed phenylbenzoisoquinolindiones, a group of phenylphenalenone-derived

Precursor-Directed Biosynthesis of Phenylbenzoisoquinolindione Alkaloids and the Discovery of a Phenylphenalenone-Based Plant Defense Mechanism.

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Phenylbenzoisochromenone glucosides (oxa-phenylphenalenone glucosides) occurring in some phenylphenalenone-producing plants of the Haemodoraceae undergo conversion to phenylbenzoisoquinolindiones (aza-phenylphenalenones) in extracts of Xiphidium caeruleum. Precursor-directed biosynthetic experiments
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